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- W2076144502 abstract "The azides 2a-i undergo regiospecific [3+2]-cycloaddition with the phospha-alkyne 1 to form the l,2,3,4-triazaphospholes 3a-i; in the case of the reaction with 2J, an additional silyl shift occurs resulting in the formation of 4j. The latter product can by hydrolyzed to 6 which has also been prepared independently from 1 and hydrazoic acid(7). Flash vacuum pyrolyses of the 1,2,3,4-triazaphospholes 3c and 3e produce mixtures of the isomers 13a,b and 14a,b, respectively, from which the 1,2-azaphospholes 14 can be isolated as the major reaction products." @default.
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- W2076144502 date "1987-01-01" @default.
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- W2076144502 title "Phosphorus compounds with unusual coordination - 201. 1,2,3,4- triazaphospholes by [3+2]-cycloaddition of azides to a stable phosphaalkyne" @default.
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