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- W2076147220 abstract "The dissociation kinetics of the Fe2(μ-OH)2(H2O)84+ complex was studied in aqueous solution at 25.0 °C, 1.0 M NaClO4, and pH < 3.0, by the stopped-flow method. A mechanism involving the following three pathways is proposed: (I) Fe2(μ-OH)2(H2O)84+ ⇌ 2Fe(OH)(H2O)52+; (II) Fe2(μ-OH)2(H2O)84+ + H+ ⇌ Fe(OH)(H2O)52+ + Fe(H2O)63+; (III) Fe2(μ-OH)2(H2O)84+ ⇌ Fe2(μ-OH)2(OH)(H2O)73+ + H+; Fe2(μ-OH)2(OH)(H2O)73+ ⇌ Fe(OH)(H2O)52+ + Fe(OH)2(H2O)42+." @default.
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- W2076147220 date "1998-12-23" @default.
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- W2076147220 title "New Reaction Path in the Dissociation of the Fe<sub>2</sub>(μ-OH)<sub>2</sub>(H<sub>2</sub>O)<sub>8</sub><sup>4+</sup> Complex" @default.
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- W2076147220 doi "https://doi.org/10.1021/ic980813c" @default.
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