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• W2076161422 abstract "The complex [Mo(C6F5)(CO)2(η-C7H7)] can be reduced either chemically or electrochemically by one electron. Electrochemical studies suggest that the reduction is followed by a rapid but reversible structural change. The orange intermediate reduction product has not yet been isolated in pure form. Chemical reduction with sodium amalgam in tetrahydrofuran in the presence of trimethyl phosphite initially forms this orange product, but precipitation with hexane yields the pale yellow zerovalent σ-aryl molybdenum complex Na[cis-mer-Mo(C6F5)(CO)2{P(OMe)3}3], in which the cycloheptatrienyl ligand has been displaced by three trimethyl phosphite groups. This complex has been fully characterized by IR, 1H and 31P NMR spectroscopy and X-ray crystallography." @default.
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• W2076161422 date "1992-01-01" @default.
• W2076161422 modified "2023-09-25" @default.
• W2076161422 title "Synthesis and characterization of Na[cis-mer-Mo(C6F5)(CO)2{P(OMe)3}3]" @default.
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• W2076161422 doi "https://doi.org/10.1039/dt9920000521" @default.
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