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• W2076164951 abstract "The hydroformylation of the differently protected glucal derivatives 3,4,6-tri-O-acetyl-d-glucal, 3,4,6-tri-O-benzyl-d-glucal and 3,4,6-tri-O-methyl-d-glucal was carried out with rhodium catalytic systems, and 2-formyl derivatives were obtained as the main products in yields of 58%, 68%, and 55% respectively, when [Rh2(μ-OMe)2(COD)2]/P(O-o-tBuC6H4)3 was used. The bulky phosphite needs to be used as auxiliary ligand to achieve the hydroformylation of these highly hindered cyclic olefins. A mechanistic cycle is proposed which explains the regio- and stereoselectivity of the reaction. The mononuclear rhodium complex trans-[RhCl(CO)(P(O-o-tBuC6H4)3)2] was isolated at the end of the catalytic reaction by breaking the dinuclear complexes used as catalyst precursors. To confirm the characterization of trans-[RhCl(CO)(P(O-o-tBuC6H4)3)2], a separate synthesis was carried out which isolated crystals suitable for an X-ray determination." @default.
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• W2076164951 date "1998-06-01" @default.
• W2076164951 modified "2023-10-11" @default.
• W2076164951 title "Regio- and Stereoselective Hydroformylation of Glucal Derivatives with Rhodium Catalysts" @default.
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• W2076164951 doi "https://doi.org/10.1021/om971010k" @default.
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