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• W2076166511 abstract "Abstract Dioxo and oxoperoxo molybdenum(VI) complexes, I – III , containing the non-labile bidentated oxazolinyl-pyridine ligand 1 , were used as catalytic precursors in the epoxidation of cyclooctene and ( R )-limonene, to explore the nature of the catalytic species. The high diastereoselectivity showed by I and II towards limonene epoxide formation ( trans / cis - 8  = 4/1) could be justified by the kinetic resolution observed to give the double epoxide ( 9 ), but also by the olefin coordination to the metal centre due to the presence of a labile ligand (isothiocyanate). 95 Mo NMR monitoring experiments of complex II in the presence of ( R )-limonene, together with conductivity measurements, showed the formation of an ionic metallic species (1:1 electrolyte). These results point to a bimetallic species where one of the metal atoms is coordinated to the olefin by the dissociation of the isothiocyanate group, remaining coordinated the spectator chiral ligand, which is the responsible of the selectivity observed." @default.
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• W2076166511 date "2008-06-01" @default.
• W2076166511 modified "2023-10-18" @default.
• W2076166511 title "Molybdenum(VI)-catalysed olefin epoxidation: Structure and reactivity study" @default.
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• W2076166511 doi "https://doi.org/10.1016/j.ica.2008.01.037" @default.
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