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- W2076173524 endingPage "1302" @default.
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- W2076173524 abstract "The electrochemical properties of the monomeric complex [(η5-C5H5)(μ-η5:η1-C5H4(CH2)2P(C6H5)2TiCl2] 1 and the heterobimetallic complex [(η5-C5H5)(μ-η5:η1-C5H4(CH2)2P(C6H5)2TiCl2][RuCl2(C6H4(CH3)(C3H7))] 2 have been studied by cyclic voltammetry, controlled potential electrolysis and rotating disk electrode voltammetry. An unexpected electron transfer between the two heterobimetallic atoms has been observed. This transfer takes place via an intramolecular interaction, hence via a chloride bridge. Electrochemical simulation has been carried out to verify experimental results and to obtain the kinetic constant of the proposed square scheme." @default.
- W2076173524 created "2016-06-24" @default.
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- W2076173524 date "2005-01-01" @default.
- W2076173524 modified "2023-09-23" @default.
- W2076173524 title "Evidence of intramolecular electron transfer between two metallic atoms in a bimetallic complex by electrochemical methods" @default.
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- W2076173524 doi "https://doi.org/10.1039/b507665j" @default.
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