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• W2076173770 abstract "Abstract Cr 2 O 3 film on structural material as hydrogen permeation barrier can be applied in many areas such as hydrogen storage devices, vacuum solar receivers and fusion reactors. In this study, the Cr 2 O 3 film was prepared by MOCVD on 316L stainless steel using chromium(III) acetylacetonate as precursor. The film was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). The hydrogen permeation inhibition performance of films was investigated by deuterium permeation experiment. The 366 nm thick Cr 2 O 3 film on 316L could reduce the deuterium permeability by 24–117 times at 823–973 K, revealing efficient inhibition to hydrogen permeation. The Cr 2 O 3 film is dense, crack-free and has a corundum structure which possesses a more stable structure than a metastable phase or an amorphous phase. Moreover, the crystalline Cr 2 O 3 could be easily obtained by MOCVD at a low temperature, e.g. 773 K." @default.
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• W2076173770 date "2014-01-01" @default.
• W2076173770 modified "2023-09-26" @default.
• W2076173770 title "Preparation of Cr2O3 film by MOCVD as hydrogen permeation barrier" @default.
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• W2076173770 doi "https://doi.org/10.1016/j.fusengdes.2013.11.005" @default.
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