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- W2076173785 abstract "Abstract The ternary imide Li 2 Mg(NH) 2 is considered to be one of the most promising on-board hydrogen storage materials due to its high reversible hydrogen capacity of 5.86 wt%, favorable thermodynamic properties and good cycling stability. In this work, Li 2 Mg(NH) 2 was synthesized by dynamically dehydrogenating a mixture of Mg(NH 2 ) 2 –2LiH up to 280 °C under different gas (Ar and H 2 ) and pressures (0–9.0 bar). The crystal structure of Li 2 Mg(NH) 2 was found to depend on the gas back pressure in the dehydrogenation process. The crystal structure of Li 2 Mg(NH) 2 and the dehydrogenation/rehydrogenation properties of the Mg(NH 2 ) 2 –2LiH system strongly depend on the gas back pressure in the dehydrogenation process due to the effect of the pressure on the dehydrogenation kinetics. This study provides a new approach for improving the hydrogen storage properties of the amide–hydride systems." @default.
- W2076173785 created "2016-06-24" @default.
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- W2076173785 date "2014-10-01" @default.
- W2076173785 modified "2023-10-16" @default.
- W2076173785 title "Effect of gas back pressure on hydrogen storage properties and crystal structures of Li 2 Mg(NH) 2" @default.
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- W2076173785 doi "https://doi.org/10.1016/j.ijhydene.2014.09.013" @default.
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