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- W2076184435 abstract "The structure and absolute configurations of two compounds having composition (CH3C5H4)Mo(CO)2 [HCPhRNC(Ph)NHCPhR′] were established by X-ray diffraction methods. MOCPME [R CH3, R′H]: orthorhombic, space group P212121; a = 10.998(6), b = 12.728(7), c = 18.622(7) Å V = 2607 Å3, Z = 4 molecules/unit cell. MOCP2 [R = CH3, R′CH3]: triclinic, space group P1; a = 9.451(4), b = 11.803(5), c = 12.436(9) Å, α = 93.11(5)°, β = 95.31(5)°, γ = 100.06(5)°. V = 1357 Å3, Z = 2 molecules/unit cell. Both are thermodynamically preferred stereoisomers and as such show the typical conformation with the side phenyl rings facing the apical Cp. MOCPME has the absolute configuration (S; C)(R; Mo). MOCP2 bears optically active substituents at both benzamidine ligand nitrogens and is (S; C)(R; C). For MOCP2, asymmetry arises from the conformation of the molecule in the solid state but should average out in solution. The conformational effects of methylating the Cp were studied A rationale is provided for the orientation of the phenyl rings with respect to the Cp ring, which does not appeal to packing forces." @default.
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- W2076184435 date "1986-04-01" @default.
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- W2076184435 title "The conformations and absolute configurations of two preferred diastereoisomers having composition (CH3C5 H4)Mo(CO)2 [HCPhRNC(Ph)NHCPhR′]" @default.
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- W2076184435 doi "https://doi.org/10.1016/s0020-1693(00)84592-2" @default.
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