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• W2076193722 startingPage "11408" @default.
• W2076193722 abstract "The Pd(0)-catalyzed allylic cross-coupling of homoallylic tosylate substrates using boronic acids and pinacol esters is reported. The reaction uses 2-(4,5-dihydro-2-oxazolyl)quinoline (quinox) as a ligand and is performed at ambient temperature. The scope of the reaction is broad in terms of both the boronate transmetalating reagent and the substrate and includes secondary tosylates. Mechanistic studies support an alkene-mediated S(N)2-type stereoinvertive oxidative addition of unactivated primary and secondary alkyl tosylates." @default.
• W2076193722 created "2016-06-24" @default.
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• W2076193722 date "2012-07-06" @default.
• W2076193722 modified "2023-09-26" @default.
• W2076193722 title "Palladium-Catalyzed Allylic Cross-Coupling Reactions of Primary and Secondary Homoallylic Electrophiles" @default.
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• W2076193722 doi "https://doi.org/10.1021/ja305403s" @default.
• W2076193722 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3412144" @default.
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