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- W2076197855 abstract "A study was carried out on the effect of pressure up to 1400 MPa on the Diels-Alder reaction between furan and methyl acrylate at 20‡C. At atmospheric pressure, the reaction proceeds with 20% yield after two months, while it proceeds at 1400 MPa with 70% yield after 2.5 h. The observed volumetric activation effect (−δVp≠) of this reaction decreases relatively slightly with increasing pressure and its value at 0.1 MPa (20 cm3/mole) is markedly less than the change in volume upon reaction (−δV0=29 cm3/mole). The ratio of the endo and exo isomers formed is 2.6 and is independent of the pressure." @default.
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- W2076197855 date "2010-08-21" @default.
- W2076197855 modified "2023-09-25" @default.
- W2076197855 title "ChemInform Abstract: Effect of Pressure on the Diels-Alder Reaction Between Furan and Methyl Acrylate." @default.
- W2076197855 doi "https://doi.org/10.1002/chin.199227082" @default.
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