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- W2076209220 abstract "The kinetics of the reduction of colloidal MnO 2 by glyphosate has been investigated spectrophotometrically in an aqueous and micellar (cetyltrimethylammonium bromide, sodium lauryl sulfate) media. The reaction follows first-order kinetics with respect to colloidal MnO 2 in both the aqueous and micellar media. The rate of oxidation increases with increase in [glyphosate] in the lower concentration range but becomes independent at its higher concentrations. The addition of both the anionic (NaLS) and cationic (CTAB) micelles increased the rate of reduction of colloidal MnO 2 by glyphosate while the nonionic TX-100 micelles did not influence the rate of reaction. In both aqueous and micellar media, the oxidation of glyphosate occurs through its adsorption over colloidal MnO 2 surface. The reaction in micellar media was treated by considering the pseudophase model. The values of reaction rates and binding constants in the presence of micelles were determined." @default.
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- W2076209220 date "2011-04-05" @default.
- W2076209220 modified "2023-09-24" @default.
- W2076209220 title "Kinetics of Reduction of Colloidal MnO2 by Glyphosate in Aqueous and Micellar Media" @default.
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- W2076209220 doi "https://doi.org/10.1155/2011/243519" @default.
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