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- W2076209962 abstract "Poly(di-n-alkylsiloxane)s substituted with ethyl up to hexyl side chains are capable of forming a columnar mesophase with a nearly hexagonal unit cell. The polymer chains are stretched, but both the backbone as well as the alkyl side chains are conformationally disordered. The stability of the mesophase (i.e. its temperature interval) strongly increases on going from ethyl to butyl substitution, and remains almost constant on going from butyl to hexyl side chains. It decreases upon decreasing molecular weight of the polymer chains, or if defects are introduced into the side chains. Introduction of side chains that facilitate intermolecular dipolar interactions or introduce rigidity stabilizes the columnar mesophase." @default.
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- W2076209962 date "1997-01-01" @default.
- W2076209962 modified "2023-09-23" @default.
- W2076209962 title "Columnar mesophase behavior of Poly(Di-n-alkylsiloxane)s" @default.
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- W2076209962 doi "https://doi.org/10.1016/s0079-6700(97)00019-1" @default.
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