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- W2076215581 abstract "The adsorption of triethylamine on mercury from aqueous 0.1 M NaOH was determined both from interfacial tension measurements by the drop-time method and from capacitive charge measurements by the single potential-step chronocoulometric method. The relative accuracies of these two methods were compared. Adsorption at constant charge satisfies the Frumkin isotherm roughly with a charge-dependent attractive interaction factor, whereas adsorption at constant potential is characterized by a practically potential-independent Frumlkin interaction factor. The adsorption properties at constant charge were interpreted on the basis of a monolayer model of H-bonded water molecules and solute dipoles with local order, and were compared critically with those of the primary isomer, n-hexylamine." @default.
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- W2076215581 date "1988-11-01" @default.
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- W2076215581 title "Adsorption of triethylamine at the mercury/water interphase from charge and interfacial tension measurements" @default.
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- W2076215581 doi "https://doi.org/10.1016/0022-0728(88)80019-6" @default.
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