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- W2076241520 endingPage "430" @default.
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- W2076241520 abstract "σ-(Trichloro-2-thienyl) derivatives of iron, nickel and manganese have been prepared from 2-lithiotrichlorothiophene and various transition metal halides. These new compounds exhibit enhanced thermal and oxidative stabilities in a manner analogous to pentahalophenyl-transition metal derivatives. 2-Thienylpentacarbonyl-manganese, a compound of limited stability, has been obtained from the reaction of thenoyl chloride and Na[Mn(CO)5]. Attempts to isolate Diels-Alder adducts which would indicate decomposition of 2-lithiotrichlorothiophene to 2,3-dichlorothiophyne have been largely unsuccessful. A reaction between bis(trichloro-2-thienyl)mercury and tetraphenylcyclopentadienone has produced 2,3-dichloro-4,5,6,7-tetraphenyl-thianaphthene in good yield. The latter may be formed via either an aryne or an addition-elimination process." @default.
- W2076241520 created "2016-06-24" @default.
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- W2076241520 date "1968-08-01" @default.
- W2076241520 modified "2023-09-27" @default.
- W2076241520 title "Perhaloaryl-metal chemistry III. σ-(trichloro-2-thienyl) derivatives of transition metals and related studies" @default.
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- W2076241520 doi "https://doi.org/10.1016/s0022-328x(00)82771-0" @default.
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