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- W2076252023 abstract "ZSM-5 and faujasite, which are aluminosilicate zeolites with different compositions, were synthesized without using organic structure-directing agents, and the changes in the medium-range order during the crystallization of ZSM-5 and faujasite were characterized by high-energy X-ray diffraction (HEXRD) technique. It is found that that the amorphous aluminosilicates have larger fraction of 4 membered ring (4R), compared to 6 membered ring (6R) that is the most dominant in amorphous silica. Furthermore, HEXRD measurements reveal that changes in the medium-range order are characteristic for each zeolite although crystallizations of both zeolites proceeded via a similar way: that is, the dissolution of amorphous precursors to solution followed by the nucleation and crystal growth of zeolite from the soluble species. In ZSM-5 crystallization, no major changes in the medium-range order are observed although slight decrease of the fraction of 4R is confirmed. On the other hand, clear changes in the medium-range order, especially on the ordering of 4R and 6R are confirmed in faujasite crystallization." @default.
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- W2076252023 date "2009-01-01" @default.
- W2076252023 modified "2023-10-01" @default.
- W2076252023 title "Changes in the medium-range order during crystallization of aluminosilicate zeolites characterized by high-energy X-ray diffraction technique" @default.
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- W2076252023 doi "https://doi.org/10.2109/jcersj2.117.277" @default.
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