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- W2076256317 abstract "Abstract The thermodynamics of molecular association in aqueous sodium dodecyl-sulfate (NaDDS) solutions at 25°C is investigated using isothermal titration, adiabatic titration and conventional calorimetry. The resulting heat effect due to micelle formation at the critical micelle concentration (c.m.c.) is 0.52±0.04 kcal/mole. The equilibrium constant, enthalpy and entropy change values for the interaction of Na + with the sulfate group at the micelle surface are calculated from the thermometric titration data. No measurable interaction between Na + and DDS − below the c.m.c. is observed. The degree of ionic dissociation as a function of NaDDS concentration is calculated and discussed." @default.
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- W2076256317 date "1971-09-01" @default.
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- W2076256317 title "A calorimetric investigation of micelle formation in aqueous sodium dodecylsulfate solutions" @default.
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- W2076256317 doi "https://doi.org/10.1016/0040-6031(71)80014-x" @default.
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