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- W2076256323 abstract "Fourteen tetraalkylammonium alkanesulfonate, perfluoroalkanesulfonate, and benzene- and pentafluorobenzenesulfonate salts possessing useful chromatographic properties were synthesized. All salts had wide liquid temperature ranges with an upper column operating temperature limit in the range 160–220°C and yielded efficient column packings. The substitution of fluorine for hydrogen in the alkanesulfonate chain resulted in a general reduction in solute non-specific and proton donor interactions accompanied by an increase in solute electron donor interactions. These findings are rationalized in terms of the weak dispersive interactions for solutes with the perfluoroalkane side chains and the ability of fluorine to effect changes in the electron density of the sulfonate group through its inductive effect. On over half the salts studied retention is shown to depend on both gas—liquid partitioning and interfacial adsorption for a wide range of solutes but the relative importance and magnitude of the adsorption contribution to retention is not simply related to the structure of the salts or the incorporation of fluorine into the anion." @default.
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- W2076256323 title "Changes in retention and polarity accompanying the replacement of hydrogen by fluorine in tetraalkylammonium alkyl- and arylsulfonate salts used as stationary phases in gas chromatography" @default.
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- W2076256323 doi "https://doi.org/10.1016/s0021-9673(00)96321-0" @default.
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