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- W2076256667 abstract "The reaction of the ammonia diol [(NH3)4Rh(OH)2Rh(NH3)4]4+with H2O2 Yields among other products a peroxo-bridged dimeric species [(NH3)4Rh(O2)(OH)Rh(NH3)3(H2O)](CIO4)3. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P21/n and lattice constants a=12.269 (5) Å, b=10.769(4) Å, c=15.964(4) Å, β=107.17(3)°. The dihedral angle of the RhOORh group in the bimetallic ring deviates by 62δ from planarity. The peroxo-bridged complex was found to disproportionate in 1M HCIO4 and a red superoxo-bridged complex. [(NH3)4Rh(O2)(OH)Rh(NH3)3(H2O)](NO3)4, was isolated. Its structure was solved by single-crystal X-ray diffraction. The crystals are orthorhombic with space group Pna 2, and lattice constants a=14.997(5) Å, b=11.952(4) Å, C=10.489(4) Å. The dihedral angle off the RhOORh group deviates by 7δ from planarity." @default.
- W2076256667 created "2016-06-24" @default.
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- W2076256667 date "1984-12-19" @default.
- W2076256667 modified "2023-09-23" @default.
- W2076256667 title "Synthesis and Crystal Structure of a Peroxo-Bridged Binuclear Rhodium (III) Complex and its Superoxo-Bridged Analogue" @default.
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- W2076256667 doi "https://doi.org/10.1002/hlca.19840670825" @default.
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