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• W2076264776 abstract "In an effort to utilize the cationic cobalt(III) complex, [carbonato bis(1,10-phenanthroline)cobalt(III)] + as an binding agent (anion receptor) for the sulphur oxoanions ( S 2 O 3 2 - , S 4 O 6 2 - , S 2 O 8 2 - ), three complex salts of composition [Co(phen) 2 CO 3 ] [Co(phen) 2 (S 2 O 3 )]·5·5H 2 O ( 1 ), [Co(phen) 2 CO 3 ] 2 S 4 O 6 ·7H 2 O ( 2 ) and [Co(phen) 2 CO 3 ] 2 S 2 O 8 ·4H 2 O ( 3 ) were synthesized and characterized by UV/Visible, IR, NMR and conductance measurements. The molecular structure of complex salts 1 – 3 were determined by single crystal X-ray crystallography which revealed the presence of discrete ions and lattice water molecules in the solid state. A strong network of hydrogen bond interactions through the weak second sphere interactions (C–H···O) and strong interactions of type O–H … O (water) besides the electrostatic interactions play a very important role in stabilizing the crystal lattice. The solubility product measurements, X-ray structure analyses and formation of these salts suggest that cation, [Co(phen) 2 CO 3 ] + present in [Co(phen) 2 CO 3 ]Cl·5H 2 O may be used as an anion receptor for the sulphur oxoanions S 2 O 3 2 - , S 4 O 6 2 - and S 2 O 8 2 - ions." @default.
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• W2076264776 date "2009-06-01" @default.
• W2076264776 modified "2023-10-18" @default.
• W2076264776 title "Anion binding through second sphere coordination: Synthesis, characterization and X-ray structures of cationic carbonato bis(1,10-phenanthroline)cobalt(III) complex with sulphur oxoanions" @default.
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• W2076264776 doi "https://doi.org/10.1016/j.molstruc.2009.03.004" @default.
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