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- W2076271253 endingPage "4582" @default.
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- W2076271253 abstract "Steady-state fluorescence spectra were measured for 1,8-naphthahlimide-linker-phenothiazine dyads (NI-L-PTZ, where L = octamethylenyl ((CH2)8) and 3,6,9-trioxaundecyl ((CH2CH2O)3C2H4)), NI-C8-PTZ and NI-O-PTZ, as well as the NI derivatives substituted on the nitrogen atom with various linker groups without PTZ as the reference NI molecule in n-hexane. Normal fluorescence peaks were observed at 367-369 nm in all NI molecules together with a broader emission around 470 nm, which is assigned to the excimer emission between the NI in the singlet excited state (1NI*) and the NI moiety of another NI molecule (1[NI/NI]*). In addition, a broad peak around 600 nm was observed only for NI-L-PTZ, which is assigned to an intramolecular exciplex emission between donor (PTZ) and acceptor (NI) moieties in the excited singlet state, 1[NI-L-NI]*. The formation of an intramolecular exciplex corresponds to the existence of a conformer with a weak face-to-face interaction between the NI and PTZ moieties in the excited state because of the long and flexible linkers. The excited-state dynamics of the NI molecules in n-hexane were established by means of time-resolved fluorescence spectroscopy." @default.
- W2076271253 created "2016-06-24" @default.
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- W2076271253 date "2006-02-14" @default.
- W2076271253 modified "2023-10-13" @default.
- W2076271253 title "Intramolecular Exciplex and Intermolecular Excimer Formation of 1,8-Naphthalimide−Linker−Phenothiazine Dyads" @default.
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- W2076271253 doi "https://doi.org/10.1021/jp056078p" @default.
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