FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076273504> ?p ?o ?g. }

• W2076273504 endingPage "1810" @default.
• W2076273504 startingPage "1805" @default.
• W2076273504 abstract "We report new experimental data and a general, mechanism-based structure−reactivity relationship for the pyrolysis of long-chain n-alkylcyclohexanes. The relationship has as its foundation the previously deduced free-radical reaction mechanism for alkylcyclohexane pyrolysis. The model is general because it incorporates the effect of the alkyl chain length on the global kinetics by accounting for the chain-length-dependent reaction path degeneracy of the initiation, β-scission, and hydrogen-abstraction steps. The global kinetics determined from the model for pyrolyses at 400 °C and an initial reactant concentration of 0.13 mol/L are in good accord with the experimentally determined rate constants for nine different n-alkylcyclohexanes with aliphatic substituents ranging from butyl (n-C4) to octadecyl (n-C18). A sensitivity analysis reveals that the rate constants for initiation, termination, and β-scission to form a primary radical had the greatest influence on the calculated pyrolysis rate. This work provides an example of how a mechanism-based analytical rate equation, rather than some empirical reactivity index, can be used as the basis for a structure−reactivity relationship for hydrocarbon pyrolysis." @default.
• W2076273504 created "2016-06-24" @default.
• W2076273504 creator A5000699619 @default.
• W2076273504 creator A5004960218 @default.
• W2076273504 creator A5072755247 @default.
• W2076273504 date "2001-03-23" @default.
• W2076273504 modified "2023-09-25" @default.
• W2076273504 title "Pyrolysis Kinetics for Long-Chain <i>n</i>-Alkylcyclohexanes" @default.
• W2076273504 cites W1969618137 @default.
• W2076273504 cites W1974332632 @default.
• W2076273504 cites W2001177810 @default.
• W2076273504 cites W2014172572 @default.
• W2076273504 cites W2025606737 @default.
• W2076273504 cites W2025762817 @default.
• W2076273504 cites W2041218731 @default.
• W2076273504 cites W2041413718 @default.
• W2076273504 cites W2049698271 @default.
• W2076273504 cites W2062999433 @default.
• W2076273504 cites W2067593044 @default.
• W2076273504 cites W2146974207 @default.
• W2076273504 cites W2325701934 @default.
• W2076273504 doi "https://doi.org/10.1021/ie0007973" @default.
• W2076273504 hasPublicationYear "2001" @default.
• W2076273504 type Work @default.
• W2076273504 sameAs 2076273504 @default.
• W2076273504 citedByCount "11" @default.
• W2076273504 countsByYear W20762735042014 @default.
• W2076273504 countsByYear W20762735042016 @default.
• W2076273504 countsByYear W20762735042020 @default.
• W2076273504 countsByYear W20762735042023 @default.
• W2076273504 crossrefType "journal-article" @default.
• W2076273504 hasAuthorship W2076273504A5000699619 @default.
• W2076273504 hasAuthorship W2076273504A5004960218 @default.
• W2076273504 hasAuthorship W2076273504A5072755247 @default.
• W2076273504 hasConcept C121332964 @default.
• W2076273504 hasConcept C139066938 @default.
• W2076273504 hasConcept C142724271 @default.
• W2076273504 hasConcept C147597530 @default.
• W2076273504 hasConcept C147789679 @default.
• W2076273504 hasConcept C148898269 @default.
• W2076273504 hasConcept C161790260 @default.
• W2076273504 hasConcept C168931907 @default.
• W2076273504 hasConcept C178790620 @default.
• W2076273504 hasConcept C185592680 @default.
• W2076273504 hasConcept C204787440 @default.
• W2076273504 hasConcept C2776910235 @default.
• W2076273504 hasConcept C2777207669 @default.
• W2076273504 hasConcept C2780263894 @default.
• W2076273504 hasConcept C36663273 @default.
• W2076273504 hasConcept C36759035 @default.
• W2076273504 hasConcept C62520636 @default.
• W2076273504 hasConcept C65024703 @default.
• W2076273504 hasConcept C71924100 @default.
• W2076273504 hasConcept C75473681 @default.
• W2076273504 hasConcept C81022585 @default.
• W2076273504 hasConcept C93391505 @default.
• W2076273504 hasConcept C97355855 @default.
• W2076273504 hasConceptScore W2076273504C121332964 @default.
• W2076273504 hasConceptScore W2076273504C139066938 @default.
• W2076273504 hasConceptScore W2076273504C142724271 @default.
• W2076273504 hasConceptScore W2076273504C147597530 @default.
• W2076273504 hasConceptScore W2076273504C147789679 @default.
• W2076273504 hasConceptScore W2076273504C148898269 @default.
• W2076273504 hasConceptScore W2076273504C161790260 @default.
• W2076273504 hasConceptScore W2076273504C168931907 @default.
• W2076273504 hasConceptScore W2076273504C178790620 @default.
• W2076273504 hasConceptScore W2076273504C185592680 @default.
• W2076273504 hasConceptScore W2076273504C204787440 @default.
• W2076273504 hasConceptScore W2076273504C2776910235 @default.
• W2076273504 hasConceptScore W2076273504C2777207669 @default.
• W2076273504 hasConceptScore W2076273504C2780263894 @default.
• W2076273504 hasConceptScore W2076273504C36663273 @default.
• W2076273504 hasConceptScore W2076273504C36759035 @default.
• W2076273504 hasConceptScore W2076273504C62520636 @default.
• W2076273504 hasConceptScore W2076273504C65024703 @default.
• W2076273504 hasConceptScore W2076273504C71924100 @default.
• W2076273504 hasConceptScore W2076273504C75473681 @default.
• W2076273504 hasConceptScore W2076273504C81022585 @default.
• W2076273504 hasConceptScore W2076273504C93391505 @default.
• W2076273504 hasConceptScore W2076273504C97355855 @default.
• W2076273504 hasIssue "8" @default.
• W2076273504 hasLocation W20762735041 @default.
• W2076273504 hasOpenAccess W2076273504 @default.
• W2076273504 hasPrimaryLocation W20762735041 @default.
• W2076273504 hasRelatedWork W1964687069 @default.
• W2076273504 hasRelatedWork W1967788951 @default.
• W2076273504 hasRelatedWork W1989280951 @default.
• W2076273504 hasRelatedWork W2042094163 @default.
• W2076273504 hasRelatedWork W2048559292 @default.
• W2076273504 hasRelatedWork W2060940060 @default.
• W2076273504 hasRelatedWork W2393243605 @default.
• W2076273504 hasRelatedWork W2950124773 @default.
• W2076273504 hasRelatedWork W3137141880 @default.
• W2076273504 hasRelatedWork W4232459072 @default.
• W2076273504 hasVolume "40" @default.
• W2076273504 isParatext "false" @default.
• W2076273504 isRetracted "false" @default.
• W2076273504 magId "2076273504" @default.

• next