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- W2076273635 abstract "Abstract Experimental phase behavior data are reported for three hyperbranched polyester polymers, Boltorn H20 (B-H20), Boltorn H2004 (B-H2004), and Boltorn U3000 (B-U3000) in supercritical ethane, propane, propylene, CO2, and dimethyl ether (DME) at temperatures to 450 K and pressures to 200 MPa. B-H20 has 100% hydroxyl terminal groups, B-H2004 has 60% saturated C6 and C8 hydrocarbon terminal groups, and B-U3000 has 90% unsaturated C16 and C18 hydrocarbon terminal groups. Cloud point, liquid–vapor, and liquid–liquid–vapor phase transitions are measured with a high-pressure, variable-volume, view cell for each Boltorn polymer at ∼5 wt% in solution. B-H20, with 100% hydroxyl terminal groups, only dissolves in DME, which is expected to hydrogen bond to the polymer hydroxyl groups. At the other extreme, B-U3000, with long chain, nonpolar hydrocarbon terminal groups, is significantly more soluble in nonpolar ethane and propane compared to propylene, CO2, or DME." @default.
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- W2076273635 date "2014-11-01" @default.
- W2076273635 modified "2023-09-26" @default.
- W2076273635 title "High-pressure phase behavior of boltorn hyperbranched polymers in supercritical fluids" @default.
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- W2076273635 doi "https://doi.org/10.1016/j.fluid.2014.09.010" @default.
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