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- W2076278164 abstract "Abstract The data available in literature on the vibration spectra of complex uranyl compounds indicate that the stretching vibration frequencies of the UO2+ 2 group depend not only on the composition of the coordination sphere, but also on the outer surrounding of the complex anion. The outer-sphere cation, in case of uranyl complexes, acts as a competitor of the uranyl group to form bonds with, ligands. At the same time, as a result of decrease in the electron density localised on the U-F bonds, the strength of these bonds becomes less." @default.
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- W2076278164 date "1971-01-01" @default.
- W2076278164 modified "2023-09-25" @default.
- W2076278164 title "A Spectroscopic Study of Outer-Sphere Interaction in M3UO2F5Complexes" @default.
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- W2076278164 doi "https://doi.org/10.1080/00387017108078637" @default.
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