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- W2076284186 abstract "Abstract From an analysis of the photoelectrically recorded Raman band of acetylene at 3950 cm −1 , which contains contributions from ν 1 +ν 4 and its hot bands, ν 3 +ν 5 in Fermi resonance with ν 2 +ν 4 +2ν 5 , and the Q ‐branch of 2ν 2 , some anharmonicity constants were determined. In particular x 22 = −7.4 cm −1 was obtained directly for the first time, other constants are revised due to a more complete consideration of the resonance perturbations. A computer simulation of the ν 4 fundamental and the ν 1 +ν 4 combination band shows excellent agreement with the experimental spectra." @default.
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- W2076284186 date "1981-10-01" @default.
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- W2076284186 title "Determination of anharmonicity constants from the Raman spectrum of gaseous acetylene" @default.
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- W2076284186 doi "https://doi.org/10.1002/jrs.1250110516" @default.
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