FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076288595> ?p ?o ?g. }

• W2076288595 endingPage "1119" @default.
• W2076288595 startingPage "1119" @default.
• W2076288595 abstract "Hydroxyl resonances in NMR spectra potentially provide much structural information in the form of chemical shifts, J couplings, NOES and isotope shifts but this information is largely destroyed by intermolecular exchange; these applications are briefly reviewed and the exchange mechanism is described. It is shown that exchange of the hydroxyl protons of alcohols in chloroform solution can be slowed simply by dilution of the alcohol because the rate-determining step for exchange requires a bimolecular encounter. When exchange is slow on the NMR chemical shift and coupling timescales, separate signals are observed for each different hydroxyl site, allowing spectral and structural assignment by correlation techniques such as decoupling, COSY, and related techniques. In addition, the limiting chemical shifts and the concentrations required for fast exchange are characteristically different for protons which are intramolecularly hydrogen-bonded. It is shown that propane-1,3-diol and ethane-1,2-diol are strongly hydrogen-bonded intramolecularly in chloroform solution." @default.
• W2076288595 created "2016-06-24" @default.
• W2076288595 creator A5001143064 @default.
• W2076288595 creator A5015924749 @default.
• W2076288595 date "1994-01-01" @default.
• W2076288595 modified "2023-09-27" @default.
• W2076288595 title "Improving the use of hydroxyl proton resonances in structure determination and NMR spectral assignment: inhibition of exchange by dilution" @default.
• W2076288595 cites W1615937227 @default.
• W2076288595 cites W1963587313 @default.
• W2076288595 cites W1980839289 @default.
• W2076288595 cites W1988812248 @default.
• W2076288595 cites W1991576282 @default.
• W2076288595 cites W1993458330 @default.
• W2076288595 cites W1993610474 @default.
• W2076288595 cites W2002832239 @default.
• W2076288595 cites W2003987840 @default.
• W2076288595 cites W2019744006 @default.
• W2076288595 cites W2026312450 @default.
• W2076288595 cites W2036085903 @default.
• W2076288595 cites W2061406062 @default.
• W2076288595 cites W2064293093 @default.
• W2076288595 cites W2069461446 @default.
• W2076288595 cites W2071456671 @default.
• W2076288595 cites W2072590167 @default.
• W2076288595 cites W2081418680 @default.
• W2076288595 cites W2085356202 @default.
• W2076288595 cites W2317641545 @default.
• W2076288595 cites W239858185 @default.
• W2076288595 doi "https://doi.org/10.1039/p19940001119" @default.
• W2076288595 hasPublicationYear "1994" @default.
• W2076288595 type Work @default.
• W2076288595 sameAs 2076288595 @default.
• W2076288595 citedByCount "25" @default.
• W2076288595 countsByYear W20762885952012 @default.
• W2076288595 countsByYear W20762885952013 @default.
• W2076288595 countsByYear W20762885952014 @default.
• W2076288595 countsByYear W20762885952015 @default.
• W2076288595 crossrefType "journal-article" @default.
• W2076288595 hasAuthorship W2076288595A5001143064 @default.
• W2076288595 hasAuthorship W2076288595A5015924749 @default.
• W2076288595 hasConcept C103319777 @default.
• W2076288595 hasConcept C111429119 @default.
• W2076288595 hasConcept C121332964 @default.
• W2076288595 hasConcept C1276947 @default.
• W2076288595 hasConcept C147597530 @default.
• W2076288595 hasConcept C147789679 @default.
• W2076288595 hasConcept C166950319 @default.
• W2076288595 hasConcept C178790620 @default.
• W2076288595 hasConcept C185592680 @default.
• W2076288595 hasConcept C2779515768 @default.
• W2076288595 hasConcept C2781144210 @default.
• W2076288595 hasConcept C32909587 @default.
• W2076288595 hasConcept C4839761 @default.
• W2076288595 hasConcept C512968161 @default.
• W2076288595 hasConcept C54516573 @default.
• W2076288595 hasConcept C62520636 @default.
• W2076288595 hasConcept C67787023 @default.
• W2076288595 hasConcept C71240020 @default.
• W2076288595 hasConcept C75079739 @default.
• W2076288595 hasConcept C96618451 @default.
• W2076288595 hasConcept C97355855 @default.
• W2076288595 hasConceptScore W2076288595C103319777 @default.
• W2076288595 hasConceptScore W2076288595C111429119 @default.
• W2076288595 hasConceptScore W2076288595C121332964 @default.
• W2076288595 hasConceptScore W2076288595C1276947 @default.
• W2076288595 hasConceptScore W2076288595C147597530 @default.
• W2076288595 hasConceptScore W2076288595C147789679 @default.
• W2076288595 hasConceptScore W2076288595C166950319 @default.
• W2076288595 hasConceptScore W2076288595C178790620 @default.
• W2076288595 hasConceptScore W2076288595C185592680 @default.
• W2076288595 hasConceptScore W2076288595C2779515768 @default.
• W2076288595 hasConceptScore W2076288595C2781144210 @default.
• W2076288595 hasConceptScore W2076288595C32909587 @default.
• W2076288595 hasConceptScore W2076288595C4839761 @default.
• W2076288595 hasConceptScore W2076288595C512968161 @default.
• W2076288595 hasConceptScore W2076288595C54516573 @default.
• W2076288595 hasConceptScore W2076288595C62520636 @default.
• W2076288595 hasConceptScore W2076288595C67787023 @default.
• W2076288595 hasConceptScore W2076288595C71240020 @default.
• W2076288595 hasConceptScore W2076288595C75079739 @default.
• W2076288595 hasConceptScore W2076288595C96618451 @default.
• W2076288595 hasConceptScore W2076288595C97355855 @default.
• W2076288595 hasIssue "9" @default.
• W2076288595 hasLocation W20762885951 @default.
• W2076288595 hasOpenAccess W2076288595 @default.
• W2076288595 hasPrimaryLocation W20762885951 @default.
• W2076288595 hasRelatedWork W1964753427 @default.
• W2076288595 hasRelatedWork W2010635321 @default.
• W2076288595 hasRelatedWork W2028126338 @default.
• W2076288595 hasRelatedWork W2040281521 @default.
• W2076288595 hasRelatedWork W2041555345 @default.
• W2076288595 hasRelatedWork W2053106862 @default.
• W2076288595 hasRelatedWork W2094262682 @default.
• W2076288595 hasRelatedWork W2107429814 @default.
• W2076288595 hasRelatedWork W2967999959 @default.
• W2076288595 hasRelatedWork W4243743992 @default.
• W2076288595 isParatext "false" @default.
• W2076288595 isRetracted "false" @default.

• next