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- W2076291413 abstract "The correlation of solvent effects on the fluorine-19 nuclear magnetic resonance chemical shifts and fluorine-proton coupling constants of three halogenated ether anesthetics (enflurane, 2-chloro-1-(difluoromethoxy)-1,1,2-trifluoroethane, fluroxene, (2,2,2-trifluoroethoxy)ethene, and methoxyflurane, 2,2-dichioro-1,1-difluoro-1-methoxy-ethane) with a variety of solvent parameters, including refractive index and solvent cohesive energy density, is examined. Correlations of these solvent parameters with 19F chemical shifts are improved when potentially interactive solvents such as carbonyl compounds, some alcohols, amines, and water are excluded from the calculations. Correlation coefficients are highest for a series of n-alkanes. Measured vicinal H-F coupling constants of fluroxene and methoxyflurane are larger in electron-donor solvents than in non-electron-donor solvents. On the other hand, measured geminal H-F coupling constants in enflurane decrease by 1.0 Hz on moving from non-electron-donor solvents to electron-donor solvents. Anesthetic :solvent interactions are discussed with regard to solvent dispersion properties." @default.
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- W2076291413 date "1978-04-01" @default.
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- W2076291413 title "Interaction of fluorinated ether anesthetics with solvents" @default.
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