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- W2076291882 abstract "Radical copolymerization of cyclohexene (M1) with N-phenylmaleimide (M2) was carried out with 2,2′-azobis(isobutyronitrile) as an initiator in various solvents at 50°C. The copolymerization of cyclohexene with N-phenylmaleimide in chloroform and dioxane proceeded in a homogeneous system to give an alternating copolymer over a wide range of the comonomer composition in the feed. The initial rate of the copolymerization (Rp) was dependent on the monomer composition and was a maximum at about 65 mol% of N-phenylmaleimide in the feed. A solvent effect on the Rp and the reactivity ratio was investigated in this copolymerization system, i.e., copolymerization in benzene produced a higher Rp than that in chloroform and in dioxane, while in chloroform produced a higher alternating tendency compared with those in benzene and in dioxane (r1=0, r2=0.012 in chloroform; r1=0, r2=0.081 in benzene and r1=0, r2=0.073 in dioxane). The copolymer was characterized by 1H-NMR spectrum." @default.
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- W2076291882 date "2000-10-26" @default.
- W2076291882 modified "2023-10-18" @default.
- W2076291882 title "FREE RADICAL COPOLYMERIZATION OF N-PHENYLMALEIMIDE WITH CYCLOHEXENE" @default.
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- W2076291882 doi "https://doi.org/10.1081/ma-100101166" @default.
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