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• W2076293002 abstract "A brief historic overview of Pt/Sn-catalyzed hydroformylation as well as recent advances in the hydroformylation of internal alkenes is provided. This serves as background for the results obtained with the [Pt(Sixantphos)Cl(2)] system, for which the molecular structure and the spectroscopic data are described. Insitu UV/Vis-spectroscopic studies have revealed rapid formation of the corresponding Pt-stannate complex upon reaction with SnCl(2), whereas high-pressure insitu IR-spectroscopy showed formation of a Pt-CO species and a short-lived Pt-H species under syngas, as well as rapid evolution of aldehyde product upon addition of 1-octene to the preformed catalyst in the IR autoclave. The hydroformylation of 1-octene and the i-octenes has been performed. For the internal alkenes, selective tandem isomerization/hydroformylation towards n-nonanal is observed with this catalyst system." @default.
• W2076293002 created "2016-06-24" @default.
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• W2076293002 date "2007-01-01" @default.
• W2076293002 modified "2023-09-27" @default.
• W2076293002 title "Platinum-catalyzed hydroformylation of terminal and internal octenes" @default.
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• W2076293002 doi "https://doi.org/10.1039/b615428j" @default.
• W2076293002 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17325781" @default.
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