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- W2076295634 abstract "Hybrids of vinblastine and phomopsin, designed by a molecular modelling study, were elaborated in order to target tubulin. The key step of the synthesis (fragmentation and insertion of vindoline) was mediated by an internal N-carboxyanhydride (or O-acylcarbamate). This reaction was diastereospecific and addition of silver salts could reverse the diastereoselectivity. Even if the synthesized compounds are inactive, this synthesis represents an original example of a C-N fragmentation mediated by a N-carboxyanhydride." @default.
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- W2076295634 date "2011-01-01" @default.
- W2076295634 modified "2023-10-10" @default.
- W2076295634 title "Elaboration of vinblastine hybrids using a reactive in situ generated N-carboxyanhydride" @default.
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- W2076295634 doi "https://doi.org/10.1039/c0ob01065k" @default.
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