Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076295928> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W2076295928 endingPage "192" @default.
- W2076295928 startingPage "191" @default.
- W2076295928 abstract "The mechanism of the first cation radical cycloaddition reaction to be discovered, the cyclodimerization of N-vinylcarbazole, has now been studied by means of a stereochemical criterion. The cyclodimerization of N-(cis-2-deuteriovinyl)carbazole is observed to be non-stereospecific, yielding a cyclodimer in which approximately 80% of the deuterium atoms are cis to the carbazolyl group and 20% are trans to the carbazolyl group. This result stands in contrast to the stereospecific cyclodimerization of trans- and cis-anethole and other stereospecific cation radical cyclobutanation reactions which have been studied more recently. The cyclodimerization of N-vinylcarbazole must therefore occur via a stepwise path, involving an intermediate distonic cation radical, as originally proposed by the Ledwith group. Further, the gauche conformation of the distonic cation radical is implied to be preferred over the anti form." @default.
- W2076295928 created "2016-06-24" @default.
- W2076295928 creator A5022559982 @default.
- W2076295928 creator A5081972282 @default.
- W2076295928 date "2000-01-01" @default.
- W2076295928 modified "2023-09-26" @default.
- W2076295928 title "The mechanism of the prototype cation radical cycloaddition reaction: the cyclodimerization of N-vinylcarbazole" @default.
- W2076295928 cites W2055464740 @default.
- W2076295928 cites W3005283329 @default.
- W2076295928 doi "https://doi.org/10.1039/a907940h" @default.
- W2076295928 hasPublicationYear "2000" @default.
- W2076295928 type Work @default.
- W2076295928 sameAs 2076295928 @default.
- W2076295928 citedByCount "7" @default.
- W2076295928 countsByYear W20762959282019 @default.
- W2076295928 crossrefType "journal-article" @default.
- W2076295928 hasAuthorship W2076295928A5022559982 @default.
- W2076295928 hasAuthorship W2076295928A5081972282 @default.
- W2076295928 hasConcept C121332964 @default.
- W2076295928 hasConcept C135502975 @default.
- W2076295928 hasConcept C145148216 @default.
- W2076295928 hasConcept C148898269 @default.
- W2076295928 hasConcept C155647269 @default.
- W2076295928 hasConcept C161790260 @default.
- W2076295928 hasConcept C178790620 @default.
- W2076295928 hasConcept C185592680 @default.
- W2076295928 hasConcept C187921627 @default.
- W2076295928 hasConcept C193609823 @default.
- W2076295928 hasConcept C2776127813 @default.
- W2076295928 hasConcept C2779664164 @default.
- W2076295928 hasConcept C62520636 @default.
- W2076295928 hasConcept C65024703 @default.
- W2076295928 hasConcept C75473681 @default.
- W2076295928 hasConcept C93391505 @default.
- W2076295928 hasConcept C96444392 @default.
- W2076295928 hasConceptScore W2076295928C121332964 @default.
- W2076295928 hasConceptScore W2076295928C135502975 @default.
- W2076295928 hasConceptScore W2076295928C145148216 @default.
- W2076295928 hasConceptScore W2076295928C148898269 @default.
- W2076295928 hasConceptScore W2076295928C155647269 @default.
- W2076295928 hasConceptScore W2076295928C161790260 @default.
- W2076295928 hasConceptScore W2076295928C178790620 @default.
- W2076295928 hasConceptScore W2076295928C185592680 @default.
- W2076295928 hasConceptScore W2076295928C187921627 @default.
- W2076295928 hasConceptScore W2076295928C193609823 @default.
- W2076295928 hasConceptScore W2076295928C2776127813 @default.
- W2076295928 hasConceptScore W2076295928C2779664164 @default.
- W2076295928 hasConceptScore W2076295928C62520636 @default.
- W2076295928 hasConceptScore W2076295928C65024703 @default.
- W2076295928 hasConceptScore W2076295928C75473681 @default.
- W2076295928 hasConceptScore W2076295928C93391505 @default.
- W2076295928 hasConceptScore W2076295928C96444392 @default.
- W2076295928 hasIssue "2" @default.
- W2076295928 hasLocation W20762959281 @default.
- W2076295928 hasOpenAccess W2076295928 @default.
- W2076295928 hasPrimaryLocation W20762959281 @default.
- W2076295928 hasRelatedWork W145122482 @default.
- W2076295928 hasRelatedWork W1970729021 @default.
- W2076295928 hasRelatedWork W1994262006 @default.
- W2076295928 hasRelatedWork W1996543192 @default.
- W2076295928 hasRelatedWork W2004112662 @default.
- W2076295928 hasRelatedWork W2025618101 @default.
- W2076295928 hasRelatedWork W2060244427 @default.
- W2076295928 hasRelatedWork W2552750765 @default.
- W2076295928 hasRelatedWork W2792755238 @default.
- W2076295928 hasRelatedWork W2950762726 @default.
- W2076295928 isParatext "false" @default.
- W2076295928 isRetracted "false" @default.
- W2076295928 magId "2076295928" @default.
- W2076295928 workType "article" @default.