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- W2076308250 abstract "Abstract Heretofore, it has been assumed that the Rydberg (3s) doublets appearing in the absorption spectrum of ethylene derive their intensity from dipole allowedness. This mechanism is consistent with a vibrational assignment of the spacing between members of the doublet pairs as methylene twisting, v′4, in the R state. Herein is presented an analysis based on the assumption that the Rydbergs derive intensity via vibronic stealing from the underlying V → N band. This mechanism presents, for the first time, an explanation for the doublet nature of the Rydbergs by offering two tenable vibrational modes through which intensity stealing can occur-v′8 and v′4 + v′10. This predicts a doublet spacing of v′4 + v′10 - v′8, which provides excellent agreement between ground and excited state isotopic ratios (C2D4 against C2H4), namely, 0.595 in N versus 0.594 in R. Predictions are made as to the positions of the dipole allowed bands, as well as the values of v′2, v′4, v′6 and v′10 in the R states of C2H4 and C2D4." @default.
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- W2076308250 date "1975-01-01" @default.
- W2076308250 modified "2023-10-08" @default.
- W2076308250 title "The Rydberg Doublets of Ethylene; Intensity Stealing in Mono-Olefins" @default.
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- W2076308250 doi "https://doi.org/10.1080/00387017508067325" @default.
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