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- W2076314651 abstract "The ion-molecule reactions in gaseous ammonia have been examined at pressures up to 2 torr in a high-pressure mass spectrometer. Solvation of ammonium ions as well as other ions in both NH3 and ND3 studies has been observed. The stability of the solvates NH4+(NH3)n diminishes with increasing degree of solvation. The effect of the energy of the ionizing electrons on the yields of solvated and other ions has been studied. Evidence for the formation of excited states of NH4+, NH4+, NH3, NH4+(NH3)2, etc., and collisional de-excitation processes was obtained. Only NH4+ ions reach thermodynamic equilibrium at the ion-source pressures used in these experiments." @default.
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- W2076314651 title "Ion-molecule reactions in ammonia at high pressures" @default.
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