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- W2076329161 abstract "Diphenyloctyl phosphate (DPOF) was used as a flame-retardant additive to improve the thermal stability of electrolyte for lithium-ion batteries. Effects of DPOF on the flammability and conductivity of electrolyte were investigated. A series of electrochemical measurements and scanning electron microscopy (SEM) were employed to investigate the compatibility of DPOF with LiNi1/3Co1/3Mn1/3O2 (NCM) and artificial graphite (AG), respectively. The results show that DPOF can effectively reduce the flammability of the electrolytes, corresponding with a small decrease of conductivity. Additionally, DPOF has no distinct effect on SEI film formation of artificial graphite, and the capacity of Li/AG half-cell with 5% DPOF is higher than that of base electrolyte, while the cycling stability of NCM/Li cells becomes worse with the increasing ratio of DPOF. Electrochemical impedance spectroscopy shows that the charge-transfer resistance of NCM/Li cells with DPOF is much larger than that of cells without DPOF in the 50th cycle, while there is no distinct variation on resistances of Li/AG cells with or without DPOF." @default.
- W2076329161 created "2016-06-24" @default.
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- W2076329161 date "2012-01-01" @default.
- W2076329161 modified "2023-10-13" @default.
- W2076329161 title "Compatibility of Diphenyloctyl Phosphate as Flame-Retardant Additive with LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub>/Artificial Graphite Cells" @default.
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- W2076329161 doi "https://doi.org/10.1149/2.058208jes" @default.
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