FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076337448> ?p ?o ?g. }

• W2076337448 endingPage "5502" @default.
• W2076337448 startingPage "5498" @default.
• W2076337448 abstract "Abstract Correcting an earlier report, the reaction of 1‐phenyl‐3,4‐dimethylphosphole ( 1a ) with an excess amount of dimethyl acetylenedicarboxylate (DMAD) at room temperature affords the stable cyclopentadienylidenephosphorane 3a resulting from unexpected deoxygenation of initially formed [phosphole + 2DMAD] adduct 2a by the starting phosphole. The identity of 3a was established by X‐ray crystal structure analysis. DFT calculations on a model [1+2] adduct similar to 2a shows a bent allenic structure and an ambident reactivity for the terminal carbon of the (DMAD) 2 chain. Cyclopentadienylidenephosphorane 3b is also obtained with 1‐benzylphosphole 1b . With 1‐stannylphosphole 1c , a 1:3 adduct with a seven‐membered ring (i.e., 5 ) is obtained. It was also characterized by X‐ray crystal structure analysis. Finally, with 1‐benzyl‐2‐benzoylphosphole 1d , the P lone pair has lost its nucleophilicity and a [4+2] cycloaddition takes place with the dienol tautomer of the unsaturated ketone to give phosphindole 6 , also characterized by X‐ray." @default.
• W2076337448 created "2016-06-24" @default.
• W2076337448 creator A5031793056 @default.
• W2076337448 creator A5039678457 @default.
• W2076337448 creator A5053255592 @default.
• W2076337448 creator A5074641469 @default.
• W2076337448 creator A5091860187 @default.
• W2076337448 date "2010-08-16" @default.
• W2076337448 modified "2023-09-26" @default.
• W2076337448 title "Dimethyl Acetylenedicarboxylate and Phospholes: A Variety of Reaction Pathways" @default.
• W2076337448 cites W1971109428 @default.
• W2076337448 cites W1975332935 @default.
• W2076337448 cites W1984495851 @default.
• W2076337448 cites W1987494748 @default.
• W2076337448 cites W1989902578 @default.
• W2076337448 cites W2002066609 @default.
• W2076337448 cites W2002766543 @default.
• W2076337448 cites W2003390292 @default.
• W2076337448 cites W2007627089 @default.
• W2076337448 cites W2012995996 @default.
• W2076337448 cites W2014237228 @default.
• W2076337448 cites W2017801769 @default.
• W2076337448 cites W2069709151 @default.
• W2076337448 cites W2108132042 @default.
• W2076337448 cites W246159814 @default.
• W2076337448 cites W2950786493 @default.
• W2076337448 doi "https://doi.org/10.1002/ejoc.201000723" @default.
• W2076337448 hasPublicationYear "2010" @default.
• W2076337448 type Work @default.
• W2076337448 sameAs 2076337448 @default.
• W2076337448 citedByCount "10" @default.
• W2076337448 countsByYear W20763374482012 @default.
• W2076337448 countsByYear W20763374482014 @default.
• W2076337448 countsByYear W20763374482015 @default.
• W2076337448 countsByYear W20763374482016 @default.
• W2076337448 countsByYear W20763374482017 @default.
• W2076337448 countsByYear W20763374482019 @default.
• W2076337448 countsByYear W20763374482020 @default.
• W2076337448 countsByYear W20763374482021 @default.
• W2076337448 crossrefType "journal-article" @default.
• W2076337448 hasAuthorship W2076337448A5031793056 @default.
• W2076337448 hasAuthorship W2076337448A5039678457 @default.
• W2076337448 hasAuthorship W2076337448A5053255592 @default.
• W2076337448 hasAuthorship W2076337448A5074641469 @default.
• W2076337448 hasAuthorship W2076337448A5091860187 @default.
• W2076337448 hasConcept C108204754 @default.
• W2076337448 hasConcept C111233374 @default.
• W2076337448 hasConcept C115624301 @default.
• W2076337448 hasConcept C142724271 @default.
• W2076337448 hasConcept C155647269 @default.
• W2076337448 hasConcept C161790260 @default.
• W2076337448 hasConcept C178790620 @default.
• W2076337448 hasConcept C178907741 @default.
• W2076337448 hasConcept C185592680 @default.
• W2076337448 hasConcept C204787440 @default.
• W2076337448 hasConcept C2776017861 @default.
• W2076337448 hasConcept C2776910235 @default.
• W2076337448 hasConcept C2777600838 @default.
• W2076337448 hasConcept C2779664164 @default.
• W2076337448 hasConcept C2779778602 @default.
• W2076337448 hasConcept C32909587 @default.
• W2076337448 hasConcept C46000676 @default.
• W2076337448 hasConcept C71240020 @default.
• W2076337448 hasConcept C71924100 @default.
• W2076337448 hasConcept C8010536 @default.
• W2076337448 hasConceptScore W2076337448C108204754 @default.
• W2076337448 hasConceptScore W2076337448C111233374 @default.
• W2076337448 hasConceptScore W2076337448C115624301 @default.
• W2076337448 hasConceptScore W2076337448C142724271 @default.
• W2076337448 hasConceptScore W2076337448C155647269 @default.
• W2076337448 hasConceptScore W2076337448C161790260 @default.
• W2076337448 hasConceptScore W2076337448C178790620 @default.
• W2076337448 hasConceptScore W2076337448C178907741 @default.
• W2076337448 hasConceptScore W2076337448C185592680 @default.
• W2076337448 hasConceptScore W2076337448C204787440 @default.
• W2076337448 hasConceptScore W2076337448C2776017861 @default.
• W2076337448 hasConceptScore W2076337448C2776910235 @default.
• W2076337448 hasConceptScore W2076337448C2777600838 @default.
• W2076337448 hasConceptScore W2076337448C2779664164 @default.
• W2076337448 hasConceptScore W2076337448C2779778602 @default.
• W2076337448 hasConceptScore W2076337448C32909587 @default.
• W2076337448 hasConceptScore W2076337448C46000676 @default.
• W2076337448 hasConceptScore W2076337448C71240020 @default.
• W2076337448 hasConceptScore W2076337448C71924100 @default.
• W2076337448 hasConceptScore W2076337448C8010536 @default.
• W2076337448 hasIssue "28" @default.
• W2076337448 hasLocation W20763374481 @default.
• W2076337448 hasOpenAccess W2076337448 @default.
• W2076337448 hasPrimaryLocation W20763374481 @default.
• W2076337448 hasRelatedWork W2001349386 @default.
• W2076337448 hasRelatedWork W2013971629 @default.
• W2076337448 hasRelatedWork W2068492944 @default.
• W2076337448 hasRelatedWork W2076337448 @default.
• W2076337448 hasRelatedWork W2094546426 @default.
• W2076337448 hasRelatedWork W2217922018 @default.
• W2076337448 hasRelatedWork W2951203388 @default.
• W2076337448 hasRelatedWork W3196205954 @default.
• W2076337448 hasRelatedWork W4246348712 @default.

• next