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• W2076339975 endingPage "631" @default.
• W2076339975 startingPage "627" @default.
• W2076339975 abstract "Scanning tunneling microscopy (STM) has been employed to investigate the chirality of monophosphine compounds that are highly efficient chiral ligands in transition-metal-catalyzed organic transformations. The absolute configuration of 1-(2-diphenyphosphino-1-naphthyl)isoquinoline enantiomers with axial chirality was discriminated directly by the marker group, PPh(2) substitutes. Although the two enantiomer molecules adsorb on a Cu(111) surface and form well-defined (4 x 4) structures, the positions of PPh(2) substitutes in the molecular adlayers are different. The mirror symmetry between two adlayers is demonstrated. On the basis of STM results, structural models are proposed to interpret the chiral adsorption. The results presented here supply a straightforward method for axial chirality analysis in adsorbed adlayers by STM." @default.
• W2076339975 created "2016-06-24" @default.
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• W2076339975 date "2003-12-18" @default.
• W2076339975 modified "2023-10-10" @default.
• W2076339975 title "Absolute Configuration of Monodentate Phosphine Ligand Enantiomers on Cu(111)" @default.
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• W2076339975 doi "https://doi.org/10.1021/ac0347720" @default.
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• W2076339975 hasPublicationYear "2003" @default.
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