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- W2076349733 abstract "The isomerization reaction of 2,4,4-trimethyl-1-pentene to 2,4,4-trimethyl-2-pentene was studied. In contrast to the general rule for alkene stability, an excess of the α-alkene (2,4,4-trimethyl-1-pentene) was observed in the thermodynamic equilibrium. The result is explained in terms of the molecular structure: the large and bulky substituents in 2,4,4-trimethyl-2-pentene cause steric tension and make the molecule less stable. A reaction enthalpy of 3.51 ± 0.03 kJ mol-1, i.e., endothermic reaction, and a reaction entropy of −0.47 ± 0.10 J mol-1 K-1 were determined from the experimental data of the isomerization reaction." @default.
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- W2076349733 date "2001-01-18" @default.
- W2076349733 modified "2023-10-11" @default.
- W2076349733 title "Reaction Equilibrium in the Isomerization of 2,4,4-Trimethyl Pentenes" @default.
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- W2076349733 doi "https://doi.org/10.1021/ie000526s" @default.
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