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- W2076351609 abstract "Micelles made up of lipophilic ligand 2a and Cu2+ or Zn2+ ions show catalytic properties in the cleavage of the pnitrophenylester of picolinic acid (PNPP). in the case of the Cu+ complex comparison with the non-micellar model 3a and the Omethylated siblings clearly shows how only the supramolecular assembly leads to catalysis with involvement of the hydroxyl as the nucleophile. A stereochemical modification of the complex in the aggregate is suggested as a likely explanation of the observed phenomena" @default.
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- W2076351609 title "Micellization triggers pseudo-intramolecular transacylation in Cu2+ complexes of hydrolytic metallomicelles." @default.
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- W2076351609 doi "https://doi.org/10.1016/s0040-4039(00)97735-9" @default.
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