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- W2076356270 abstract "The effective electrode potential of an ultrahigh vacuum model of the electrode-electrolyte interface was controlled through coadsorption of varying amounts of hydrogen with water on Pt(111) at 100 K. High resolution electron energy loss spectroscopy (HREELS) demonstrated formation of surface H3O+ ions upon heating > 20% saturation coverages of hydrogen with water to 150 K, indicating an effective electrode potential below the potential of zero charge (pzc). Comparison of these results with cyclic voltanunetry of well-ordered Pt(111) in weakly-adsorbing electrolytes suggests that the pzc lies around + 0.2 V RHE and that the breadth of the hydrogen regions of the voltammograms is due to potential dependent interactions between coadsorbed H and H3O+." @default.
- W2076356270 created "2016-06-24" @default.
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- W2076356270 date "1988-11-01" @default.
- W2076356270 modified "2023-09-23" @default.
- W2076356270 title "Generation of surface hydronium from water and hydrogen coadsorbed on Pt(111)" @default.
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- W2076356270 doi "https://doi.org/10.1016/0039-6028(88)90021-0" @default.
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