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• W2076370938 abstract "Inorganic–organic hybrid materials were prepared by step-wise free radical polymerization of styrene in the presence of zirconium oxo clusters of the general compositions Zr6O4(OH)4(carboxylate)12 (carboxylate = 5-norbornene-2-carboxylate or isobutyrate/methacrylate) and Zr12O8(OH)8(carboxylate)24 (carboxylate = acetate/propionate, vinylacetate, or acetate/methacrylate). Clusters with non-polymerizable ligands resulted in cluster/polystyrene blends which were soluble in toluene, whereas clusters with polymerizable ligands gave cluster-crosslinked, swellable polymers for which solvent uptake correlated with the functionality of the corresponding cluster. The onset temperatures of thermal decomposition and the glass transition temperatures of all cluster-containing polymers were higher than that of neat polystyrene, independent of whether the clusters were crosslinking or blended into the polymer." @default.
• W2076370938 created "2016-06-24" @default.
• W2076370938 creator A5031831521 @default.
• W2076370938 creator A5039153033 @default.
• W2076370938 date "2007-08-01" @default.
• W2076370938 modified "2023-09-26" @default.
• W2076370938 title "Crosslinking vs. filler effect of carboxylate-substituted zirconium oxo clusters on the thermal stability of polystyrene" @default.
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• W2076370938 doi "https://doi.org/10.1016/j.polymer.2007.06.029" @default.
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