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• W2076374414 startingPage "157" @default.
• W2076374414 abstract "The dielectric properties of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) reverse micelles in CCl4 and n-heptane have been measured in the frequency range 0.02–20 GHz as a function of W = [H2O][AOT]. A relaxation phenomenon has been observed reflecting some properties inherent the single particle dynamics. This dielectric relaxation has been found to be markedly affected by interparticle interactions. Our data, according to previous results, show that interactions in these systems depend on the oil chain length, on the molar ratio W and are significantly affected by the addition of small amounts of electrolyte. In order to achieve a deeper insight into the microscopic origin of these interactions, IR absorptions in the CO stretching region of AOT molecules have been recorded to give information on the relative population of different AOT rotational isomers in the various examined systems. The data show a clear correlation between the presence of attractive interactions and the composition of AOT rotamers, supporting the hypothesis that the intermicellar interactions are favored by a particular orientation and packing of non-polar tails of AOT molecules in the micellar microaggregate." @default.
• W2076374414 created "2016-06-24" @default.
• W2076374414 creator A5063729096 @default.
• W2076374414 creator A5071615340 @default.
• W2076374414 creator A5079424935 @default.
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• W2076374414 date "1996-09-01" @default.
• W2076374414 modified "2023-10-11" @default.
• W2076374414 title "Micellar interactions in water-in-oil microemulsions" @default.
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• W2076374414 doi "https://doi.org/10.1016/s0022-2860(96)09280-0" @default.
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