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• W2076377615 abstract "A new method is described for palladium-catalyzed allylic silylation using allylic alcohols and disilanes as precursors. The reactions proceed smoothly under mild and neutral conditions, and this method is suitable for synthesis of regio- and stereodefined allylsilanes. The presented silylation reaction can be easily extended to include synthesis of allylboronates by change of the dimetallic reagent. The presented synthetic procedure offers a broad platform for the selective synthesis of functionalized allyl metal reagents, which are useful precursors in advanced organic chemistry and natural product synthesis." @default.
• W2076377615 created "2016-06-24" @default.
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• W2076377615 date "2010-12-16" @default.
• W2076377615 modified "2023-10-17" @default.
• W2076377615 title "Palladium-Catalyzed Allylic C−OH Functionalization for Efficient Synthesis of Functionalized Allylsilanes" @default.
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• W2076377615 doi "https://doi.org/10.1021/ja1096732" @default.
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