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• W2076380959 abstract "Near-edge X-ray absorption fine structure (NEXAFS) is used to establish the CO bond length (1.25±0.05 Å), the OCO angle (124±15°) and the azimuthal orientation (along [110]) of the molecular plane of the formate catalytic intermediate adsorbed on Cu(110). Extended X-ray absorption fine structure (EXAFS) is then used to determine the CuO bond length (1.98±0.07 Å) and the adsorption site (atop copper atoms in the top (ridge) rows, with oxygen atoms near short bridge sites). The problems of obtaining reliable quantitative results from NEXAFS are discussed. The adsorption site and bond length, which agrees well with that for anhydrous copper formate, is contrasted with the much longer bond length found for this species adsorbed on Cu(100) by Stöhr et al. [Phys. Rev. Letters 54 (1985) 1256]." @default.
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• W2076380959 date "1986-05-01" @default.
• W2076380959 modified "2023-09-23" @default.
• W2076380959 title "Determination of the adsorption structure for formate on Cu(110) using SEXAFS and NEXAFS" @default.
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• W2076380959 doi "https://doi.org/10.1016/0039-6028(86)90558-3" @default.
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