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- W2076385831 abstract "The isomerization reaction of sulfur-containing light naphtha was studied. The Pd/SO42−/ZrO2-Al2O3 catalyst in which the active metal was modified into Pd indicates the stable isomerization activity, although the isomerization activity of the conventional Pt/SO42−/ZrO2-Al2O3 catalyst decreases due to the existence of sulfur in the feed. But the increase of sulfur content in feed caused a drop of the isomerization level over Pd/SO42−/ZrO2-Al2O3 catalyst. The increase in the amount of sulfur supplied to the catalyst invites the increase of the amount of Pd required for a desulfurization reaction, and leads to the decrease in the relative amount of Pd that performs the homogeneous dissociation of gaseous hydrogen. By preparing the catalysts so that the methods of the Pd addition are different, one could study the correlation between the position of Pd in SO42−/ZrO2-Al2O3 carrier and the isomerization activity. The catalyst, which forms Pd/Al2O3 shows the highest isomerization activity. This fact suggests that the optimal position of Pd in SO42−/ZrO2-Al2O3 carrier is on Al2O3 and that the high desulfurization function is obtained by the formation of Pd/Al2O3." @default.
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- W2076385831 date "2004-11-01" @default.
- W2076385831 modified "2023-09-24" @default.
- W2076385831 title "Simultaneous isomerization and desulfurization of sulfur-containing light naphtha over metal/SO42−/ZrO2-Al2O3 catalyst" @default.
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- W2076385831 doi "https://doi.org/10.1016/j.apcata.2004.07.055" @default.
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