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- W2076386543 abstract "A new 2-oxazoline with a pendant alkyne moiety, 2-(pent-4-ynyl)-2-oxazoline, 1 (PynOx), was synthesized from commercial available compounds. Polymerization of PynOx with methyl triflate as initiator and copolymerization with 2-methyl- or 2-ethyl-2-oxazoline (MeOx or EtOx) as comonomers results in well-defined water-soluble polymers of narrow molar mass distributions and predefined degrees of polymerization. Since the alkyne moiety is compatible with the living cationic polymerization, no protection group was needed. The consecutive copper-catalyzed Huisgen 1,3-dipolar cycloadditions of two different azides with the polymer bound alkynes to the 1,2,3-triazoles were quantitative." @default.
- W2076386543 created "2016-06-24" @default.
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- W2076386543 date "2006-04-25" @default.
- W2076386543 modified "2023-10-09" @default.
- W2076386543 title "Click Chemistry with Poly(2-oxazoline)s" @default.
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- W2076386543 doi "https://doi.org/10.1021/ma052515m" @default.
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