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- W2076405384 abstract "Abstract The 3-ethyl thiazolium peptide salts Boc-Thia-Leu-OMe and Boc-Thia-Leu-Phe-OMe based on the unnatural amino acid thiazolylalanine (Thia) have been prepared. After deprotonation, they reacted rapidly via the silver carbene transfer reaction with [RhCp ∗ Cl 2 ] 2 and [Ru( p -cymene)Cl 2 ] 2 to yield the corresponding thiazole-based carbene complexes 7 – 10 in acceptable yield. All new compounds were characterized by multinuclear NMR spectroscopy, mass spectrometry, and elemental analysis. These complexes constitute the first examples of thiazolylalanine-2-ylidene metal bioconjugates." @default.
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- W2076405384 date "2011-03-01" @default.
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- W2076405384 title "Organometallic peptide NHC complexes of Cp∗Rh(III) and arene Ru(II) moieties from l-thiazolylalanine" @default.
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- W2076405384 doi "https://doi.org/10.1016/j.jorganchem.2010.12.044" @default.
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