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- W2076405418 abstract "Abstract The unsymmetrical ene-dione 1b exists in solution as a mixture of two conformational isomers, A and B, in rapid equilibrium. Irradiation of 1b in this medium leads to four products, two from each conformer. In the solid state, however, compound 1b adopts a single conformation (A), and photolysis of crystals of 1b leads to a single product. The formation of one rather than two photoproducts in this instance is attributed to a unique solid state steric effect, termed steric compression." @default.
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- W2076405418 date "1985-01-01" @default.
- W2076405418 modified "2023-09-27" @default.
- W2076405418 title "Conformation-specific photochemistry in the solid state" @default.
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- W2076405418 doi "https://doi.org/10.1016/s0040-4039(00)98487-9" @default.
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