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- W2076448610 abstract "Soybean oil was partially hydrogenated with copper catalyst in an isothermal, concurrent, flow type reactor to reduce linolenate content. Reaction proceeded at one atmosphere outlet pressure; the parameters of temperature, catalyst concentration and oil flow rate (residence time) were varied. The reactor was designed to permit sampling at points along its length. Intermediate and final samples were analyzed to give total characterization of the partially hydrogenated oil. Data thus obtained were used to model and simulate the continuous hydrogenation kinetics. Linolenate selectivity is high and variations in reaction parameters appeared to have little effect. Specific isomerization values were increased as catalyst concentration increased but were unaffected by temperature and oil flow rate. Conjugated diene formation went through a maximum as the hydrogenation proceeded. Results of the copper-catalyzed continuous hydrogenations were compared to those of batch hydrogenations using the same reaction parameters." @default.
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- W2076448610 date "1979-04-01" @default.
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- W2076448610 title "Laboratory-scale continuous hydrogenation: Cooper catalysis" @default.
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- W2076448610 doi "https://doi.org/10.1007/bf02680189" @default.
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