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- W2076455465 abstract "Binuclear copper(II) complexes with amides derived from 3-amino-1-propanol and various amino acids were prepared and characterized by elemental analysis, infrared and electronic spectra and magnetic susceptibilities (78–300 K.). They exhibit a band around 28 × 103 cm−1 characteristic of alkoxo-bridged structure and show a very strong antiferromagnetic interaction. The crystal structure of one of them, [Cu2{NH2C(CH3)2 CONCH2CH2CH2O}2], was determined by the single-crystal X-ray diffraction method. Crystals are monoclinic, space group P21/n, a = 16.661(16), b = 10.256(4), c = 5.333(1) Å; β = 98.69(2)°. The structure was solved by the heavy atom method and refined by the block-diagonal least-squares method to an R factor of 0.038. The crystal structure consists of alkoxo-bridged binuclear units. The coordination geometry about the copper ion is square-planar. The structure detail is in harmony with the magnetic and spectral properties." @default.
- W2076455465 created "2016-06-24" @default.
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- W2076455465 date "1983-01-01" @default.
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- W2076455465 title "Binuclear metal complexes. LII [1]. Synthesis spectral and magnetic properties of binuclear copper(II) complexes of amides derived from 3-amino-1-propanol and various amino acids, and crystal structure of copper(II) complex of α-aminosobutyric acid derivative" @default.
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- W2076455465 doi "https://doi.org/10.1016/s0020-1693(00)91182-4" @default.
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