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- W2076455783 abstract "The configuration and conformation of the isomeric enol acetates of acetylacetone have been elucidated. P.m.r. shift data obtained by the use of tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionato)europium(III) (Eu(fod) 3 ) allow assignment of the (S)-cis conformation to both isomers. The remarkable stability of the isomer having acetyl cis to acetoxy is attributed to neighboring group interaction, a rationale consistent with p.m.r. spectroscopic data." @default.
- W2076455783 created "2016-06-24" @default.
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- W2076455783 date "1973-11-15" @default.
- W2076455783 modified "2023-10-03" @default.
- W2076455783 title "The Isomeric Enol Acetates of Acetylacetone. Evidence for an Unusual Stabilizing Interaction between <i>cis</i> Acetyl and Acetoxy Groups" @default.
- W2076455783 doi "https://doi.org/10.1139/v73-560" @default.
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